Modelling catalytic turnover frequencies in ionic liquids: the determination of the bimolecular rate constant for solvent displacement from [(C6H6)Cr(CO)2Solv] in 1-n-butyl-3-methylimidazolium hexafluorophosphate.

Konrad  Swiderski; Andrew McLean; Charles M. Gordon; D.H. Vaughan

doi:10.1039/B315781D

Modelling catalytic turnover frequencies in ionic liquids: the determination of the bimolecular rate constant for solvent displacement from [(C6H6)Cr(CO)2Solv] in 1-n-butyl-3-methylimidazolium hexafluorophosphate.

Konrad Swiderski, Andrew McLean, Charles M. Gordon, D.H. Vaughan

School of Health and Life Sciences

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

The bimolecular rate constant for solvent displacement, k(2), from [(C(6)H(6))Cr(CO)(2)Solv] by an incoming ligand has been determined in the room temperature ionic liquid, [bmim][PF(6)], and is compared to that for the same process in cyclohexane and dichloroethane

Original language	English
Pages (from-to)	590-91
Number of pages	2
Journal	ChemComm
DOIs	https://doi.org/10.1039/B315781D
Publication status	Published - 2004

Keywords

RTILs
Cohesive pressures

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abstract = "The bimolecular rate constant for solvent displacement, k(2), from [(C(6)H(6))Cr(CO)(2)Solv] by an incoming ligand has been determined in the room temperature ionic liquid, [bmim][PF(6)], and is compared to that for the same process in cyclohexane and dichloroethane ",

keywords = "RTILs, Cohesive pressures",

author = "Konrad Swiderski and Andrew McLean and Gordon, \{Charles M.\} and D.H. Vaughan",

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doi = "10.1039/B315781D",

language = "English",

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journal = "ChemComm",

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publisher = "Royal Society of Chemistry",

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Modelling catalytic turnover frequencies in ionic liquids: the determination of the bimolecular rate constant for solvent displacement from [(C6H6)Cr(CO)2Solv] in 1-n-butyl-3-methylimidazolium hexafluorophosphate. / Swiderski, Konrad ; McLean, Andrew; Gordon, Charles M. et al.
In: ChemComm, 2004, p. 590-91.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Modelling catalytic turnover frequencies in ionic liquids

T2 - the determination of the bimolecular rate constant for solvent displacement from [(C6H6)Cr(CO)2Solv] in 1-n-butyl-3-methylimidazolium hexafluorophosphate.

AU - Swiderski, Konrad

AU - McLean, Andrew

AU - Gordon, Charles M.

AU - Vaughan, D.H.

PY - 2004

Y1 - 2004

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AB - The bimolecular rate constant for solvent displacement, k(2), from [(C(6)H(6))Cr(CO)(2)Solv] by an incoming ligand has been determined in the room temperature ionic liquid, [bmim][PF(6)], and is compared to that for the same process in cyclohexane and dichloroethane

KW - RTILs

KW - Cohesive pressures

U2 - 10.1039/B315781D

DO - 10.1039/B315781D

M3 - Article

SN - 1359-7345

SP - 590

EP - 591

JO - ChemComm

JF - ChemComm

ER -