Graphene–graphite polyurethane composite based high-energy density flexible supercapacitors

Libu Manjakkal, William Taube Navaraj, Carlos García Núñez, Ravinder Dahiya

Research output: Contribution to journalArticle

Abstract

Energy autonomy is critical for wearable and portable systems and to this end storage devices with high‐energy density are needed. This work presents high‐energy density flexible supercapacitors (SCs), showing three times the energy density than similar type of SCs reported in the literature. The graphene–graphite polyurethane (GPU) composite based SCs have maximum energy and power densities of 10.22 µWh cm−2 and 11.15 mW cm−2, respectively, at a current density of 10 mA cm−2 and operating voltage of 2.25 V (considering the IR drop). The significant gain in the performance of SCs is due to excellent electroactive surface per unit area (surface roughness 97.6 nm) of GPU composite and high electrical conductivity (0.318 S cm−1). The fabricated SCs show stable response for more than 15 000 charging/discharging cycles at current densities of 10 mA cm−2 and operating voltage of 2.5 V (without considering the IR drop). The developed SCs are tested as energy storage devices for wide applications, namely: a) solar‐powered energy‐packs to operate 84 light‐emitting diodes (LEDs) for more than a minute and to drive the actuators of a prosthetic limb; b) powering high‐torque motors; and c) wristband for wearable sensors.
Original languageEnglish
Article number1802251
Number of pages13
JournalAdvanced Science
Volume6
Issue number7
Early online date13 Feb 2019
DOIs
Publication statusPublished - 3 Apr 2019

Fingerprint

Polyurethanes
Composite materials
Current density
Electric potential
Prosthetics
Energy storage
Supercapacitor
Diodes
Actuators
Surface roughness

Keywords

  • energy autonomy
  • flexible supercapacitors
  • graphite
  • photovoltaic cells
  • wearable systems

Cite this

Manjakkal, Libu ; Navaraj, William Taube ; García Núñez, Carlos ; Dahiya, Ravinder. / Graphene–graphite polyurethane composite based high-energy density flexible supercapacitors. In: Advanced Science. 2019 ; Vol. 6, No. 7.
@article{f66a87ae5aba48d48935a5674d53bb61,
title = "Graphene–graphite polyurethane composite based high-energy density flexible supercapacitors",
abstract = "Energy autonomy is critical for wearable and portable systems and to this end storage devices with high‐energy density are needed. This work presents high‐energy density flexible supercapacitors (SCs), showing three times the energy density than similar type of SCs reported in the literature. The graphene–graphite polyurethane (GPU) composite based SCs have maximum energy and power densities of 10.22 µWh cm−2 and 11.15 mW cm−2, respectively, at a current density of 10 mA cm−2 and operating voltage of 2.25 V (considering the IR drop). The significant gain in the performance of SCs is due to excellent electroactive surface per unit area (surface roughness 97.6 nm) of GPU composite and high electrical conductivity (0.318 S cm−1). The fabricated SCs show stable response for more than 15 000 charging/discharging cycles at current densities of 10 mA cm−2 and operating voltage of 2.5 V (without considering the IR drop). The developed SCs are tested as energy storage devices for wide applications, namely: a) solar‐powered energy‐packs to operate 84 light‐emitting diodes (LEDs) for more than a minute and to drive the actuators of a prosthetic limb; b) powering high‐torque motors; and c) wristband for wearable sensors.",
keywords = "energy autonomy, flexible supercapacitors, graphite, photovoltaic cells, wearable systems",
author = "Libu Manjakkal and Navaraj, {William Taube} and {Garc{\'i}a N{\'u}{\~n}ez}, Carlos and Ravinder Dahiya",
year = "2019",
month = "4",
day = "3",
doi = "10.1002/advs.201802251",
language = "English",
volume = "6",
journal = "Advanced Science",
issn = "2198-3844",
publisher = "John Wiley & Sons, Inc.",
number = "7",

}

Graphene–graphite polyurethane composite based high-energy density flexible supercapacitors. / Manjakkal, Libu; Navaraj, William Taube; García Núñez, Carlos; Dahiya, Ravinder.

In: Advanced Science, Vol. 6, No. 7, 1802251, 03.04.2019.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Graphene–graphite polyurethane composite based high-energy density flexible supercapacitors

AU - Manjakkal, Libu

AU - Navaraj, William Taube

AU - García Núñez, Carlos

AU - Dahiya, Ravinder

PY - 2019/4/3

Y1 - 2019/4/3

N2 - Energy autonomy is critical for wearable and portable systems and to this end storage devices with high‐energy density are needed. This work presents high‐energy density flexible supercapacitors (SCs), showing three times the energy density than similar type of SCs reported in the literature. The graphene–graphite polyurethane (GPU) composite based SCs have maximum energy and power densities of 10.22 µWh cm−2 and 11.15 mW cm−2, respectively, at a current density of 10 mA cm−2 and operating voltage of 2.25 V (considering the IR drop). The significant gain in the performance of SCs is due to excellent electroactive surface per unit area (surface roughness 97.6 nm) of GPU composite and high electrical conductivity (0.318 S cm−1). The fabricated SCs show stable response for more than 15 000 charging/discharging cycles at current densities of 10 mA cm−2 and operating voltage of 2.5 V (without considering the IR drop). The developed SCs are tested as energy storage devices for wide applications, namely: a) solar‐powered energy‐packs to operate 84 light‐emitting diodes (LEDs) for more than a minute and to drive the actuators of a prosthetic limb; b) powering high‐torque motors; and c) wristband for wearable sensors.

AB - Energy autonomy is critical for wearable and portable systems and to this end storage devices with high‐energy density are needed. This work presents high‐energy density flexible supercapacitors (SCs), showing three times the energy density than similar type of SCs reported in the literature. The graphene–graphite polyurethane (GPU) composite based SCs have maximum energy and power densities of 10.22 µWh cm−2 and 11.15 mW cm−2, respectively, at a current density of 10 mA cm−2 and operating voltage of 2.25 V (considering the IR drop). The significant gain in the performance of SCs is due to excellent electroactive surface per unit area (surface roughness 97.6 nm) of GPU composite and high electrical conductivity (0.318 S cm−1). The fabricated SCs show stable response for more than 15 000 charging/discharging cycles at current densities of 10 mA cm−2 and operating voltage of 2.5 V (without considering the IR drop). The developed SCs are tested as energy storage devices for wide applications, namely: a) solar‐powered energy‐packs to operate 84 light‐emitting diodes (LEDs) for more than a minute and to drive the actuators of a prosthetic limb; b) powering high‐torque motors; and c) wristband for wearable sensors.

KW - energy autonomy

KW - flexible supercapacitors

KW - graphite

KW - photovoltaic cells

KW - wearable systems

UR - http://www.mendeley.com/research/graphenegraphite-polyurethane-composite-based-highenergy-density-flexible-supercapacitors

U2 - 10.1002/advs.201802251

DO - 10.1002/advs.201802251

M3 - Article

VL - 6

JO - Advanced Science

JF - Advanced Science

SN - 2198-3844

IS - 7

M1 - 1802251

ER -